![European Journal of Chemistry](/TempFiles/eurjchem_ojs3_header.jpg)
Crystal and molecular structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex
Main Article Content
Abstract
The title compound, C32H44Br2CuN4O2S2, was synthesized from 4-bromo-N-(dibutylcarbamothioyl)benzamide ligand and copper(II)acetate. The crystal structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex was determined from single crystal X-ray diffraction studies. It crystallizes in the triclinic space group, P-1 (no. 2) with unit cell dimensions of a = 8.519(10) Å, b = 16.64(2) Å, c = 25.78(4) Å, α = 77.11(3)o, β = 85.59(3)o, γ = 89.46(2)o , Z = 4 and V = 795.8(6) Å3. The crystal structure is stabilized by weak C-H…N, C-H…S and C-H…Br hydrogen-bonding interactions.
![icon graph](\TempFiles\icon-graph.png)
![icon graph](\TempFiles\icon-pdf.png)
![icon graph](\TempFiles\icon-pdf.png)
Article Details
[1]. Ilis, M.; Bucos, M.; Dumirtrascu, F.; Circu, V. J. Mol. Struc. 2011, 987, 1-6.
http://dx.doi.org/10.1016/j.molstruc.2010.11.037
[2]. Beyer, L.; Hoyer, J.; Liebscher, J.; Hartmann, H. Z. Chem. 1981, 21(3), 81-91.
[3]. Muhl, P.; Gloe, K.; Dietze, F.; Hoyer, E.; Beyer, L. Z. Chem. 1986, 26(3), 81-94.
[4]. Koch, K. R. Coord. Chem. Rev. 2001, 216, 473-488.
http://dx.doi.org/10.1016/S0010-8545(01)00337-X
[5]. Mansuroglu, D. S.; Arslan, H.; VanDerveer, D.; Binzet G. Phosphorus, Sulfur Silicon Relat. Elem. 2009, 184(12), 3221-3230.
http://dx.doi.org/10.1080/10426500902979743
[6]. Binzet, G.; Arslan, H.; Florke, U.; Kulcu, N.; Duran, N. J. Coord. Chem. 2006, 59, 1395-1406.
http://dx.doi.org/10.1080/00958970500512633
[7]. Arslan, H.; Duran, N.; Borekci, G.; Ozer, C. K.; Akbay, C. Molecules 2009, 14(1), 519-527.
http://dx.doi.org/10.3390/molecules14010519
PMid:19169199
[8]. Saeed, S.; Rashid, N.; Ali, M.; Hussain, R. Eur. J. Chem. 2010, 1(3), 200-205.
http://dx.doi.org/10.5155/eurjchem.1.3.200-205.120
[9]. Campo, R. D.; Criado, J. J.; Garcia, E.; Hermosa, M. R.; Jimenez-Sanchez, A.; Manzano, J. L.; Monte, E. Rodriguez-Fernandez, E.; Sanz, F. J. Inorg. Biochem. 2002, 89(1-2), 74-82.
PMid:11931966
[10]. Saeed, S.; Rashid, N.; Ali, M.; Hussain, R.; Jones, P. G. Eur. J. Chem. 2010, 1(3), 221-227.
http://dx.doi.org/10.5155/eurjchem.1.3.221-227.124
[11]. Abdel, H. M. H.; Gad-Elkareem, M. A. M. G. E.; El-Adasy, A. B. A. E. A. A. M.; Othman, I. M. Phosphorus, Sulfur Silicon Relat. Elem. 2009, 184(9), 2263-2280.
http://dx.doi.org/10.1080/10426500802453658
[12]. Khan, M. H.; Bano, Q.; Nızamuddin. J. Agr. Food Chem. 1995, 43(10), 2719-2721.
http://dx.doi.org/10.1021/jf00058a032
[13]. Sacht, C.; Datt, M. S.; Otto, S.; Roodt. A. J. Chem. Soc. Dalton Trans. 2000, 24, 4579-4585.
http://dx.doi.org/10.1039/b007589m
[14]. Fuks, L.; Anuszewska, E.; Kruszewska, H.; Krowczynski, A.; Dudek, J.; Sadlej-Sosnowska, N. Trans. Metal Chem. 2010, 35(6), 639-647.
http://dx.doi.org/10.1007/s11243-010-9375-9
[15]. Khan, H.; Ahmed, M. J.; Branger, M. I. Anal. Sci. 2005, 21(5), 507-512.
http://dx.doi.org/10.2116/analsci.21.507
PMid:15913137
[16]. Saeed, A.; Khera, R. A.; Abbas, N.; Latif, M.; Sajıd, I.; Flörke, U. Turk. J. Chem. 2010, 34, 335-345.
[17]. Arslan, H.; Florke, U.; Kulcu, N.; Emen, M. F. J. Coord. Chem. 2006, 59, 223-228.
http://dx.doi.org/10.1080/00958970500270992
[18]. Mansuroglu, D. S.; Arslan, H.; Florke, U.; Kulcu, N. J. Coord. Chem. 2008, 61, 3134-3146.
http://dx.doi.org/10.1080/00958970802010567
[19]. Binzet, G.; Arslan, H.; Florke, U.; Kulcu, N. J. Coord. Chem. 2009, 62(21), 3454-3462.
http://dx.doi.org/10.1080/00958970903082200
[20]. Ugur, D.; Arslan, H.; Kulcu, N. Russ. J. Coord. Chem. 2006, 32, 669-675.
http://dx.doi.org/10.1134/S1070328406090089
[21]. Ozer, C. K.; Arslan, H.; VanDerveer, D.; Kulcu, N. Molecules 2009, 14(2), 655-666.
http://dx.doi.org/10.3390/molecules14020655
PMid:19214154
[22]. Avsar, G.; Arslan, H.; Haupt, H. J.; Kulcu, N. Turk. J. Chem. 2003, 27, 281-285.
[23]. Arslan, H.; Florke, U.; Kulcu, N.; Emen, M. F. J. Coord. Chem. 2006, 59, 223-228.
http://dx.doi.org/10.1080/00958970500270992
[24]. Arslan, H.; Kulcu, N.; Florke, U. Transit. Metal Chem. 2003, 28, 816-819.
http://dx.doi.org/10.1023/A:1026064232260
[25]. Arslan, H.; Florke, U.; Kulcu, N. J. Chem. Crystallogr. 2003, 33, 919-924.
http://dx.doi.org/10.1023/A:1027429814989
[26]. Binzet, G.; Florke, U.; Kulcu, N.; Arslan, H. Acta Crystallogr. E 2009, 65, o452-u1183.
http://dx.doi.org/10.1107/S1600536809003511
PMid:21582125 PMCid:2968555
[27]. Binzet, G.; Florke, U.; Kulcu, N.; Arslan, H. Acta Crystallogr. E 2009, 65, o427-u306.
http://dx.doi.org/10.1107/S1600536809003183
PMid:21582014 PMCid:2968358
[28]. Yesilkaynak, T.; Binzet, G.; Emen, F. M.; Flörke, U.; Külcü, N.; Arslan, H. Eur. J. Chem. 2010, 1(1), 1-5.
http://dx.doi.org/10.5155/eurjchem.1.1.1-5.3
[29]. Avsar, G.; Kulcu, N.; Arslan, H. Turk. J. Chem. 2002, 26, 607-615.
[30]. Ozpozan, N.; Ozpozan, T.; Arslan, H.; Karipcin, F.; Kulcu, N. Thermochim. Acta 1999, 336, 97-103.
http://dx.doi.org/10.1016/S0040-6031(99)00208-7
[31]. Ozpozan, N.; Arslan, H.; Ozpozan, T.; Merdivan, M.; Kulcu, N. J. Therm. Anal. Calorim. 2000, 61, 955-965.
http://dx.doi.org/10.1023/A:1010171230450
[32]. Bruker. SMART (Version 5. 62), SHELXTL (Version 6. 10) and SADABS (Version 2. 03), Bruker AXS Inc., Madison, Wisconsin, USA (2002).
[33]. Sheldrick, G. M. Acta Cryst. A 2008, 64, 112-122.
http://dx.doi.org/10.1107/S0108767307043930
PMid:18156677
[34]. Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. Appl. Cryst. J. 2009, 42, 339-341.
http://dx.doi.org/10.1107/S0021889808042726
[35]. Macrae, C. F.; Edgington, P. R.; McCabe, P.; Pidcock, E.; Shields, G. P.,; Taylor, R.; Towler, M.; Van de Streek, J. J. Appl. Cryst. 2006, 39, 453-457.
http://dx.doi.org/10.1107/S002188980600731X
[36]. Saeed, S.; Rashid, N.; Jones, P.; Hussain, R. Eur. J. Chem. 2011, 2(1), 77-82.
http://dx.doi.org/10.5155/eurjchem.2.1.77-82.183
[37]. Saeed, A.; Mumtaz, A.; Florke, U. Eur. J. Chem. 2010, 1(2), 73-75.
http://dx.doi.org/10.5155/eurjchem.1.2.73-75.34
[38]. Arslan, H.; Flörke, U.; Mansuroglu, D. S. E-J. Chem. 2011, 8(S1), S455-S461.
[39]. Binzet, G.; Flörke, U.; Külcü, N.; Arslan, H. Eur. J. Chem. 2012, 3(1), 37-39.
http://dx.doi.org/10.5155/eurjchem.3.1.37-39.591
[40]. Allen, F. H.; Kennard, O.; Watson, D. G.; Brammer, L.; Orpen, A. G.; Taylor. R. J. Chem. Soc. Perkin Trans. 1987, 2, S1-19.
http://dx.doi.org/10.1039/p298700000s1
Mersin University Research Fund, Mersin, Turkey (Project No, BAP-FBE-KB(GB)-2006-1).
Most read articles by the same author(s)
- Hakan Arslan, Graphical Contents , European Journal of Chemistry: Vol. 8 No. 1 (2017): March 2017
- Hakan Arslan, Graphical Contents , European Journal of Chemistry: Vol. 7 No. 3 (2016): September 2016
- Hakan Arslan, Graphical Contents , European Journal of Chemistry: Vol. 4 No. 1 (2013): March 2013
- Hakan Arslan, Graphical Contents , European Journal of Chemistry: Vol. 9 No. 1 (2018): March 2018
- Hakan Arslan, Graphical Contents , European Journal of Chemistry: Vol. 5 No. 4 (2014): December 2014
- Hakan Arslan, Graphical Contents , European Journal of Chemistry: Vol. 2 No. 2 (2011): June 2011
- Hakan Arslan, Graphical Contents , European Journal of Chemistry: Vol. 9 No. 2 (2018): June 2018
- Hakan Arslan, Graphical Contents , European Journal of Chemistry: Vol. 3 No. 3 (2012): September 2012
- Hakan Arslan, Graphical Contents , European Journal of Chemistry: Vol. 2 No. 4 (2011): December 2011
- Hakan Arslan, Graphical Contents , European Journal of Chemistry: Vol. 3 No. 4 (2012): December 2012
See how this article has been cited at scite.ai
scite shows how a scientific paper has been cited by providing the context of the citation, a classification describing whether it supports, mentions, or contrasts the cited claim, and a label indicating in which section the citation was made.
Downloads
Metrics
License Terms
Copyright © 2025 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).