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Synthesis and spectroscopic investigation of a new hexadentate Schiff base ligand with N2O4 donor atoms and related metal complexes
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Abstract
Five new complexes [CdH2L(NO3)]ClO4 (1), [ZnH2L](ClO4)2 (2), [NiH2L](ClO4)2 (3), [CuH2L](ClO4)2 (4) and [CoH2L](ClO4)2 (5) were prepared by reaction of a new Schiff base ligand and different metal ions in 1:1 ratios. The new Schiff base ligand H2L was synthesized by reaction of 2-(4-(2-formylphenoxy)butoxy) benzaldehyde and ethanol amine and characterized with IR, 1H and 13C NMR and elemental analysis. The synthesized complexes were also characterized by IR and elemental analysis in all cases and 1H, 13C NMR and COSY in the case of [CdH2L(NO3)]ClO4 and [ZnH2L](ClO4)2 complexes.
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Article Details
[1]. Bernhardt, P. V.; Lawrence, G. A. Coord. Chem. Rev. 1990, 104, 297-343.
http://dx.doi.org/10.1016/0010-8545(90)80045-U
[2]. Kaden, T. A. Pure Appl. Chem. 1993, 65, 1477-1483.
http://dx.doi.org/10.1351/pac199365071477
[3]. Wainwright, K. P. Coord. Chem. Rev. 1997, 166, 35-90.
http://dx.doi.org/10.1016/S0010-8545(97)00003-9
[4]. Costamagna, J.; Ferraudi, G.; Matsuhiro, B.; Campos-Valette, M.; Canales, J.; Villagran, M.; Vargas, J.; Aguirre, M. J. Coord. Chem. Rev. 2000, 196, 125-164.
http://dx.doi.org/10.1016/S0010-8545(99)00165-4
[5]. Wainwright, K. P. Inorg. Chem. 2001, 5, 293-298.
[6]. Haines, R. I. Rev.Inorg. Chem. 2002, 21, 165-169.
[7]. Frausto da Silva, J. J. R.; Williams, R. J. P. TheBiological Chemistry of the Elements, Oxford University Press, Oxford, 1991.
[8]. Parkin, G. Chem. Rev. 2004, 104, 699-768.
http://dx.doi.org/10.1021/cr0206263
[9]. Waalkes, M. P. J. Inorg. Biochem. 2000, 79, 241-244.
http://dx.doi.org/10.1016/S0162-0134(00)00009-X
[10]. Waalkes, M. P. Mutat. Res. 2003, 533, 107-120.
http://dx.doi.org/10.1016/j.mrfmmm.2003.07.011
[11]. Barszcz, B.; Jablonska-Wawrzycka, A.; Stadnicka, K.; Hodorowicz, S. A. Inorg. Chem. Comm. 2005, 8, 951-954.
http://dx.doi.org/10.1016/j.inoche.2005.07.013
[12]. Golbedaghi, R.; Salehzadeh, S.; Keypour, H.; Blackman, A. G. Polyhedron 2010, 29, 850856.
http://dx.doi.org/10.1016/j.poly.2009.09.027
[13]. Keypour, H.; Salehzadeh, S.; Pritchard, R. G.; Parish, R. V. Polyhedron 2000, 19, 1633-1637.
http://dx.doi.org/10.1016/S0277-5387(00)00444-7
[14]. Salehzadeh, S.; Golbedaghi, R.; Tidmarsh, I. S.; Al-Rasbi, N. K.; Adams, H. Polyhedron 2008, 27, 3549-3556.
http://dx.doi.org/10.1016/j.poly.2008.08.019
[15]. Atkinson, I. M.; Byriel, K. A.; Chia, P. S. K.; Kennard, C. H. L.; Leong, A. J.; Lindoy, L. F.; Lowe, M. P.; Mahendran, S.; Smith, G.; Eei, G. Aust. J. Chem. 1998, 51, 985-991.
http://dx.doi.org/10.1071/C98076
Payame Noor University, Tehran, 19395, Iran
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